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https://doi.org/10.1021/jo702275a
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Cite Journal: The Journal of Organic Chemistry |  Publication Date: Feb 12, 2008 |
 Citations: 44 |
The highly enantioselective synthesis of 2-oxo and 3-oxo pyrrolidines has been achieved by diastereoselective addition of the lithium enolate of alpha-diazoacetoacetate to chiral N-sulfinyl imines, followed by photoinduced Wolff rearrangement or Rh(II)-catalyzed intramolecular N-H insertion.
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