Abstract
The solid-state lithium-ion battery is proposed as the ultimate form of battery and has rapidly become an updated attentive research field due to its high safety and extreme temperature tolerance. However, current solid-state electrolytes hardly meet the requirement in practical applications due to its low ionic conductivity, weak mechanical properties, and poor interfacial contact between the electrolyte and the electrode. In this work, we developed a double-network-supported poly(ionic liquid)-based ionogel electrolyte (DN-Ionogel) via a one-step method. Due to its compact cross-linking structure, the leakage-free DN-Ionogel electrolyte exhibits outstanding flexibility and favorable mechanical properties. In this ionogel electrolyte, the double network favors dissociation of lithium bis(trifluoromethanesulfony)imide (LiTFSI), further resulting in remarkable ionic conductivity (1.8 × 10-3 S/cm, room temperature), wide electrochemical window (up to 5.0 V), and high lithium-ion transference number (0.33). Furthermore, the cell (LiFePO4||DN-Ionogel||Lithium) delivers a discharge capacity as high as 150.5 mAh/g, stable cyclic performance (over 200 cycles), and superior rate behavior.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.