High-field 13C solid-state NMR studies of stream humic and fulvic acids with fast magic-angle spinning

Abstract

Standard samples of stream humic and fulvic acids have been studied by high-resolution 13C solid-state NMR. The spectra have been recorded at a high (9.4 T) magnetic field using 3H 13C cross-polarization (CP) and proton high-power decoupling (HPDEC) with fast (up to 15 kHz) magic-angle spinning (MAS). The widths of the spectral lines decrease with increasing spinning rate. This is probably due to the overlap of spinning sidebands with resonances at low speeds and to a more effective averaging of anisotropic broadening at high speeds. However, fast MAS modulates the CP signal intensities, making quantitative analysis very difficult.