Abstract
We have demonstrated, for the first time, high-efficient non-destructive and non-derivative dissolution of cellulose could be achieved in cryogenic aqueous phosphoric acid. Cellulose from different sources and of varying degree of polymerization from 200 (MCC) to 2200 (cotton fabric) could be dissolved completely to afford solutions containing 5 wt%–18 wt% cellulose, from which ultra-strong and tough cellulose films of tensile strength as high as 707 MPa could be obtained using water as the coagulant. These solutions can be stored at −18 °C for extended time without noticeable degradation while desired degree of polymerization is also attainable by tuning the storage conditions. The findings of this work call for renewal attention on phosphoric acid as a promising cellulose solvent for being non-toxic, non-volatile, easy to handle, and cost-effective.
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