High-resolution risk mapping of heavy metals in soil with an integrated static-dynamic interaction model: A case study in an industrial agglomeration area in China

Abstract

Heavy metal pollution of soils in industrial agglomeration areas is an increasing concern worldwide. In this study, we traced the sources of heavy metal emissions using a positive matrix factorization (PMF) model. Accordingly, we proposed a novel static-dynamic risk interaction model incorporating multiple risk-related factors to quantify the spatial interaction of emission sources and the probability of accumulation of heavy metals on a large scale. This model was further classified using the Jenks optimization technique to predict the spatial distribution of high-risk hotspots. Our results determined four primary emission sources of heavy metals: industrial (35.01 %), natural (28.61 %), agricultural (26.07 %), and traffic (10.31 %) sources. Five levels were classified by the integrated risk coefficient (IRC), namely, from extremely high to extremely low risk. The extremely high- and high-risk hotspots constituting 41.52 % of the total area of the Zhenhai District, with IRC values ranging from 0.221 to 0.413, were mainly generated by multiple sources linked to PMF-based factors. This quantitative evaluation framework can generate a high-resolution spatially distributed pollution risk map at the grid scale (1 km), which can provide a relatively precise basis for policymaking for point-to-point soil pollution management.