Abstract
The absorption of carbon dioxide in aqueous solutions of piperazine (PZ) in a high pressure Jerguson cell was studied at high gas loadings (1.06–2.77) mo l C O 2 /mol PZ. Because of its cyclic and diamine characteristics, the reactivity and solubility of piperazine are higher than in other secondary amines. The solubility of CO 2 in aqueous solutions of piperazine was measured at (313 and 343) K for (0.3 and 1.2) M piperazine up to a pressure of 7400 kPa. The Electrolyte-NRTL model was used to correlate the solubility of CO 2 in aqueous solutions of piperazine. Eight adjustable ionic pair interaction parameters were estimated allowing for the correlation of the available experimental solubility data with an average deviation of 1–2% in CO 2 partial pressure. The model was tested by predicting published experimental literature data for both low and high gas loadings.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
