Abstract
The unique combination of high-pressure and pulse radiolysis kinetic techniques enables detailed mechanistic insight for a large variety of chemical processes to be gained. Typical examples for transition metal reactions are presented. These include ligand substitution, electron transfer, reactions of complexes with uncommon oxidation states, and reactions with radicals, including the formation and decomposition reactions of complexes with metal-carbon sigma bonds. The volumes of activation and volume profiles obtained form the basis of a critical analysis of different plausible reaction mechanisms.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
