Abstract
The design of a symmetrical solid oxide fuel cell comprising identical anode and cathode material brings numerous advantages over a conventional cell with different anode and cathode materials. In this report, A-site layered perovskite with an SmBaMn2O5+δ composition is synthesized and thoroughly investigated as the electrode material for symmetrical cells. The SmBaMn2O5+δ material with a P4/nmm structure remains stable in both reducing and oxidizing atmospheres at elevated temperatures, but with a difference of ca. 1 mol in the oxygen content per mole of SmBaMn2O5+δ between the oxidized and the reduced materials. The SmBaMn2O5+δ material shows high electrical conductivity in air and an acceptable value in 5% H2/Ar at 750–900 °C, and it exhibits outstanding catalytic activity toward oxygen reduction and hydrogen oxidization reactions with polarization resistance values of 0.066 and 0.313 Ω cm2 in air and humidified H2 at 900 °C, respectively. The power density of a laboratory-scale La0.8Sr0.2Ga0.8Mg0.2O3−...
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have