Abstract

High-purity chalcogenide glasses and optimal fiber structure design are essential to enhance fluorescence lifetime and pump absorption efficiency in a chalcogenide-based fiber laser. Here, Er3+-doped As2S3 glasses, with a low –OH concentration of only 0.023 cm−1 (0.01 ppm), were prepared by the novel purification method, and the 4I11/2 level lifetime of purified glasses was increased successfully from 2.3 ms in unpurified glass to 4.8 ms in the purified glass. Furthermore, a special chalcogenide preform with square inner double cladding (S-DCF) was designed and fabricated via a novel extrusion-stacking method for the first time. Compared with circle inner double cladding fiber and single cladding fiber, the pump absorption efficiency is increased by 2–5 times, which fits well with the simulation result by the three-dimensional ray tracing method. All the results mentioned above demonstrated that the elimination of –OH and the optimized structure of S-DCF can improve the luminescence efficiency apparently and promote the development of mid-infrared fiber laser based on Er3+-doped chalcogenide glass.

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