High-Frequency Ultrasonic Spectroscopy of Structure Gradients in Injection-Molded PEEK Using a Focusing Transducer.

Abstract

For high-performance thermoplastic materials, material behavior results from the degree of crystallization and the distribution of crystalline phases. Due to the less stiff amorphous and the stiffer and anisotropic crystalline phases, the microstructural properties are inhomogeneous. Thus, imaging of the microstructure is an important tool to characterize the process-induced morphology and the resulting properties. Using focusing ultrasonic transducers with high frequency (25 MHz nominal center frequency) enables the imaging of specimens with high lateral resolution, while wave propagation is related to the elastic modulus, density and damping of the medium. The present work shows experimental results of high-frequency ultrasonic spectroscopy (HF-US) applied to injection-molded polyether-ether-ketone (PEEK) tensile specimens with different process-related morphologies. This work presents different analysis procedures, e.g., backwall echo, time of flight and Fourier-transformed time signals, facilitating the mapping of gradual mechanical properties and assigning them to different crystalline content and morphological zones.