Abstract
Lead-free relaxor ferroelectric ceramics have attracted much attention in pulse power systems owing to their excellent energy storage performance and environmentally friendly characteristics. However, it is challenging to simultaneously achieve high energy storage density and efficiency in ferroelectric ceramics for practical applications. Herein, a novel optimization strategy is designed by introducing a linear dielectric SrZrO3 (SZ) with wide bandgap (Eg) into the BaTiO3-Bi0.5Na0.5TiO3-NaNbO3 (BT-BNT-NN) to form quaternary ceramics, disrupting long-range ferroelectric ordering and constructing weakly coupled polar nanoregions (PNRs). As a result, the recoverable energy density (Wrec) and energy storage efficiency (η) are simultaneously improved in (1-x) (BT-BNT-NN)-xSZ ceramics. At an electric field of 530 kV/cm, a Wrec of 3.37 J/cm3 and an η of 82.5 % were optimally achieved at x = 0.16 due to the formation of slim P-E loops, delayed polarization saturation, and ultra-high breakdown field strength (Eb), where the improvement of Eb is attributed to the reduction of porosity and the increase of Eg. Furthermore, the as-fabricated samples also exhibit excellent frequency and temperature stability. This study provides an effective method for developing high-performance dielectric capacitors for energy storage applications.
Published Version
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