Abstract
In this work, Pb-free Ba0.85Ca0.15Hf0.10Ti0.90O3 (BCHT) ferroelectric ceramic was synthesized via the sol-gel method and its structural, dielectric, ferroelectric, electrocaloric, and energy storage characteristics have been investigated under a low electric field of 20 kV/cm. The Rietveld refinement of XRD patterns shows good agreement with the co-existence of two phases tetragonal (P4mm) and cubic (Pm3m), with each phase contribution of 58 and 42% respectively. A volumetric porosity of around 11.5% is observed. The electrocaloric temperature change ΔT and entropy change ΔS have been estimated by an indirect approach using Maxwell relations. The room temperature value of – ΔS and ΔT are 0.207 J/Kg.K and 0.157 K respectively and a wide temperature span of 50K was observed. The room temperature observed enhanced total energy density, recoverable energy density, and energy storage efficiency were 84.43 mJ/cm3, 64.38 mJ/cm3, and 76.25 % respectively. The maximum energy storage efficiency of 85.03% was observed at 80oC. The Pb-free BCHT ceramic is a promising candidate for eco-friendly cooling and energy storage technology.
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