Abstract
Using molecular dynamics simulation, we present a comprehensive study of the volatile thermal degradation of high-density polyethylene (HDPE) across a temperature range of 300K to 1823K. We find that degradation at temperatures higher than ∼1373K generates significant quantities of reducing gases such as CHn and hydrogen molecules which are beneficial to the steelmaking industry. Our results provide a new understanding of HDPE's phase transformation from solid to gas that occurs during superheating at steelmaking's electric arc furnace environment offering a new method for eliminating end-of-life HDPE from landfill.
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