Abstract

The authors report on the high current density n-ZnO/p-Si heterojunction diode that has been fabricated by atomic layer deposition (ALD) of 70 nm thin ZnO on a p-Si substrate. While the diode was formed at four different ALD temperatures of 80, 100, 150 and 200 °C, the 100 °C processed diode showed an optimal behaviour of an on–off ratio over 3.3 × 103 and a high forward current density, ∼300 A cm−2 at 3 V. Although the highest film conductance appeared from the 200 °C deposited ZnO layer, nanometre thin SiOx was also revealed at the ZnO/p-Si interface; it might cause a high reverse leakage current level. Our high current density diode also demonstrates a fast switching performance without any reverse recovery delay, which is often observed at a usual Si p–n diode.

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