High critical current density and improved flux pinning in bulk MgB2 synthesized by Ag addition

Abstract

In the present investigation, we report a systematic study of Ag admixing in MgB2 prepared by solid-state reaction at ambient pressure. All the samples in the present investigation have been subjected to structural∕ microstructural characterization employing x-ray diffraction and transmission electron microscopic (TEM) techniques. The magnetization measurements were performed by physical property measurement system. The TEM investigations reveal the formation of MgAg nanoparticles in Ag admixed samples. These nanoparticles may enhance critical current density due to their size (∼5–20nm) which is compatible with the coherence length of MgB2 (∼5–6nm). In order to study the flux pinning effect of Ag admixing in MgB2, the evaluation of intragrain critical current density (Jc) has been carried out through magnetic measurements on the fine powdered version of the as synthesized samples. The optimum result on intragrain Jc is obtained for 10at.% Ag admixed sample at 5K. This corresponds to ∼9.23×107A∕cm2 in self-field, ∼5.82×107A∕cm2 at 1T, ∼4.24×106A∕cm2 at 3.6T, and ∼1.52×105A∕cm2 at 5T. However, intragrain Jc values for MgB2 sample without Ag admixing are ∼2.59×106, ∼1.09×106, ∼4.53×104, and 2.91×103A∕cm2 at 5K in self-field, 1T, 3.6T, and 5T, respectively. The high value of intragrain Jc for Ag admixed MgB2 superconductor has been attributed to the inclusion of MgAg nanoparticles into the crystal matrix of MgB2, which are capable of providing effective flux pinning centers. A feasible correlation between microstructural features and superconducting properties has been put forward.