Abstract
A new catalytic system formed of RhCl 3, 3H 2O as a catalyst and triethyl orthoformate, HC(OEt) 3, as a solvent showed high catalytic activity in the reaction of hydroformylation of aryl, terminal and internal alkyl alkenes, and also cycloalkenes. The addition of the triphenyl phosphite, P(OPh) 3, increased the selectivity toward the branched aldehydes with aryl alkenes.
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