Abstract
Isolation of planar [B6 H6 ] is a long-awaited goal in boron chemistry. Several attempts in the past to stabilize [B6 H6 ] were unsuccessful due to the domination of polyhedral geometries. Herein, we report the synthesis of a triple-decker sandwich complex of titanium [(Cp*Ti)2 (μ-η6 : η6 -B6 H6 )(μ-H)6 ] (1), which features the first-ever experimentally achieved nearly planar six-membered [B6 H6 ] ring, albeit within a [B6 H12 ] borate. The small deviation from planarity is a direct consequence of the predicted structural pattern of the middle ring in 24 Valence Electron Count (VEC) triple-decker complexes. The large ring size of [B6 H6 ] in 1 brings the metal-metal distance into the bonding range. However, significant electron delocalization from the M-M bonding orbital to the bridging hydrogen and B-B skeleton in the middle decreases its bond strength.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
