Abstract
In the title compound, [Mn(H2O)6]L2·2H2O, where HL is 3-carboxy-4-hydroxybenzenesulfonic acid (C7H6O6S), each MnII cation lies on an inversion center and is octahedrally coordinated by six water molecules. The L− anions do not coordinate to manganese, but act as counter-anions. The crystal structure is composed of alternating layers of [Mn(H2O)6]2+ cations and sulfonate anions. The [Mn(H2O)6]2+ cations, water molecules and L− anions are connected through a complex pattern of H-bonding interactions.
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