Abstract
A heterometallic cyanide-bridged 3d–4f heterometallic coordination polymer [Pr(DMF)4(H2O)3.5Fe(CN)6]·H2O (DMF = N,N′-dimethylformamide) has been synthesized and characterized by X-ray diffraction analysis. It crystallizes in the monoclinic space group P2(1)/n with cell parameters: a = 17.669(5) A3, b = 8.927(3) A3, c = 19.967(6) A3, β = 95.807(5)°, V = 3133.2(16) A3, Z = 4. Multiple hydrogen bonds extend the dinuclear units into a novel 2-D topological architecture of an irregular triangular lattice of iron and praseodymium ions. The magnetic properties have been investigated.
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