Abstract
Heats of transport of 0.01 m HCl, Me4NCl, and Et4NCl in H2O and 0.01 m KCl, NaCl, and CsCl in D2O were determined from the measurement of initial (homogeneous) and final (Soret steady state) thermoelectric powers of the thermocell (T)Ag−AgCl/Solution/AgCl−Ag(T+ΔT) at a mean temperature of 25°C. The results are discussed in terms of ion-solvent interaction and properties of H2O and D2O.
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