Abstract
Understanding condensation of CO2is essential for e.g designing compact heat exchangers or processes involved in Carbon Capture and Storage. However, a consistent experimental campaign for condensation of CO2on common materials is lacking. In this work, we present an experimental method and an associated laboratory setup for measuring the heat transfer properties of CO2condensation on materials commonly used in heat exchangers for the liquefaction of CO2. We have investigated the heat transfer during CO2condensation on copper, aluminum, stainless steel (316) to reveal the heat transfer dependency on surface properties. The experiments are conducted at three saturation pressures, 10, 15, and 20 bar and at substrate subcooling between 0 and 5k. The results show that the heat transfer coefficients decrease with increasing surface subcooling. It was also found that increasing the saturation pressure increases the heat transfer coefficient. The results indicate that surface roughness and surface energy affect the condensation heat transfer coefficient, and an increased roughness results in reduced heat transfer coefficients. The highest heat transfer coefficient is found for condensation on copper, for which the lowest surface roughness has been measured.
Highlights
Condensation of CO2 occurs in several stages of industrial processes
The condensation heat flux and heat transfer coefficient (HTC) increase with pressure, which is the opposite to the behavior of the Nusselt model
The results show that the heat flux and HTC are highest when condensing CO2 on Cu, and are lowest on Al and steel
Summary
Condensation of CO2 occurs in several stages of industrial processes. The need for eliminating fluorine based refrigerants due to their envi ronmental impact has, for example, opened up for CO2 as an alternative cooling fluid in heat exchangers. The global warming potential of CO2 is about three orders of magnitude lower than for the traditional re frigerants [1]. CO2 has a high triple point pressure and low critical pressure, which makes it suitable for use in cooling systems. Another example is the use of CO2 as a refrigerant in compact heat exchangers, such as in motor vehicle air-conditioning [2]. Heat exchangers with CO2 as the refrigerant or designed for liquefaction of CO2 are commonly made of e.g. copper (Cu), aluminum (Al) or stainless steel (steel) [2,3,4]
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