Abstract
AbstractSummary: The solvent‐free syndiospecific styrene polymerization as an example of a coordination polymerization has been investigated with a catalyst system consisting of η5‐octahydrofluorenyl titanium trimethoxide as a transition metal catalyst, MAO as a cocatalyst, and TIBA, in the presence of reaction products of sterically hindered phenolic compounds, usually applied as heat stabilizers of polymers. Unexpectedly, such reaction products led to a significant increase in polymerization activity of the catalyst system. Second, after deactivation of the catalyst system, such activators result in a significantly enhanced thermal stability of the syndiotactic polymers received.Effect of the P8‐activator on polymerization activity in dependence on polymerization time (molar ratio–styrene:MAO:TIBA:P:Ti = 700 000:50:25:25:1; molar ratio–phenolic compound:TIBA = 1:3.2; polymerization temperature: 50 °C).imageEffect of the P8‐activator on polymerization activity in dependence on polymerization time (molar ratio–styrene:MAO:TIBA:P:Ti = 700 000:50:25:25:1; molar ratio–phenolic compound:TIBA = 1:3.2; polymerization temperature: 50 °C).
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