Hazardous industrial filter sludge immobilization with mayenite and gypsum

Abstract

Heavy metals escaping from industrial processes and industrial waste are a significant environmental hazard all around the globe. Since they cannot be destroyed, the only way to manage the pollution is to capture and contain the hazardous components. This study focuses on stabilization-solidification of a highly toxic industrial filter slag that contains a range of different heavy metals in extremely high quantities. The stabilization-solidification treatment was executed with a mayenite and gypsum based solid cementitious binder. The major components that were monitored during the study were selenium, lead and sulphate. Different ratios of gypsum addition were tested in order to observe the effect of total sulphate content in the system to the immobilization efficiency of anionic selenium and sulphate. During the experiments, all cationic heavy metals were immobilized efficiently, most of them achieving the immobilization efficiencies of more than 99.9%. By adjusting the sulphate content of the system, the immobilization efficiency of selenium was improved from 95.669% to 99.925% and the immobilization efficiency of sulphate raised from 96.069% to above 99.964%. Controversially, the immobilization of lead was at its highest (99.999%) with high sulphate content and dropped to 98.162% as the sulphate rate decreased. The results show clearly that mayenite has good potential for stabilization-solidification applications.