Hard Magnetic Properties and Thermal Stability for TbCu<sub>7</sub>-Type SmCo<sub>6.4</sub>Si<sub>0.3</sub>Zr<sub>0.3</sub> Alloys With Sm Substituted by Various Rare-Earth Elements

Abstract

The magnetic properties and thermal stability of melt spun SmCo <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6.4</sub> Si <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</sub> Zr <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</sub> ribbons with various rare-earth (RE) elements substituted for Sm have been investigated. It is verified that the properties’ combination of SmCo <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7</sub> -based ribbons can be modified by selected RE substitution. The light RE Ce is beneficial for enhancing the saturation magnetization and the remanence, while the coercivity and thermal stability can be significantly improved by heavy REs Gd, Ho, and Er substitutions. The highest room-temperature coercivity of 1467 kA/m was achieved in the Sm <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.7</sub> Gd <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</sub> Co <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6.4</sub> Si <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</sub> Zr <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">0.3</sub> ribbon. For the temperature range of 27 °C–200 °C, Gd is the best element for enhancing the thermal stability, and the optimal temperature coefficients <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\alpha $ </tex-math></inline-formula> and <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\beta $ </tex-math></inline-formula> are −0.032%/°C and −0.269%/°C, respectively. For the range of 27 °C–400 °C, Ho is the best element to improve the thermal stability, and the values of <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\alpha $ </tex-math></inline-formula> and <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\beta $ </tex-math></inline-formula> are −0.064%/°C and −0.19%/°C, respectively.