Halogen bonded associates of iodonium salts with 18-crown-6: does structural flexibility or structural rigidity of the σ-hole donor provide efficient substrate ligation?

Alexandra A Sysoeva,Mikhail V Il’In,Alexander S Novikov,Dmitrii S Bolotin

doi:10.1039/d4nj02105c

Halogen bonded associates of iodonium salts with 18-crown-6: does structural flexibility or structural rigidity of the σ-hole donor provide efficient substrate ligation?

Alexandra A Sysoeva, Mikhail V Il’In + Show 2 more

https://doi.org/10.1039/d4nj02105c

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Journal: New Journal of Chemistry	Publication Date: Jan 1, 2024
Citations: 1

#Structural Flexibility #Efficient Ligation #Bulky Base #Cyclic Cation #Σ-hole Donor #Diphenyliodonium Cation #Iodonium Salts #Efficient Substrate #Structural Rigidity #Lewis Base

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An acyclic diphenyliodonium cation forms stronger interactions with a bulky Lewis base than a cyclic dibenziodolium cation.

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Halogen bonded associates of iodonium salts with 18-crown-6: does structural flexibility or structural rigidity of the σ-hole donor provide efficient substrate ligation?