Abstract
Mechanistic studies of H2O2 activation by complexes related to [(BPMEN)Fe(II)(CH3CN)2](2+) with electron-rich pyridines revealed that a new intermediate formed in the presence of acetic acid with a 465 nm visible band can be associated with an unusual g = 2.7 EPR signal. We postulate that this chromophore is an acylperoxoiron(III) intermediate.
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