H2, H2S gas sensing properties of rGO/GaN nanorods at room temperature: Effect of UV illumination

Abstract

In this work, reduced graphene oxide (rGO)/GaN nanorods (NRs) hybrid structure based sensors for hydrogen (H2) and hydrogen sulfide (H2S) gases has been demonstrated at room temperature. The morphological, elemental, and structural analyses were carried out by using scanning electron microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. The electrical characterization of rGO/GaN NRs hybrid structures showed good rectifying behavior compared to pristine GaN NRs. The H2 and H2S gas sensing measurements at different gas concentrations revealed that the rGO/GaN NRs exhibit superior sensing properties compared to pristine GaN NRs. In order to find the gas sensing mechanism of rGO/GaN NRs, hybrid structure sensor is also tested with NOx gas. Our experimental results revealed that the rGO/GaN NRs are good candidates for selective detection of H2S gas. The rGO/GaN NRs showed remarkably improved response under ultra-violet (λ = 365 nm) illumination, the photogenerated carriers could be responsible for increasing response of the gas sensor at 30 °C under UV illumination. In addition, humidity test of the rGO/GaN NRs sensor was also conducted in this work. Our experimental results suggested that decorating GaN NRs with solution-processable rGO is one of the effective ways to enhance the response of GaN nanostructures.