Abstract

The electron cyclotron resonance (ECR) negative ion source “Prometheus I” is operated either with high purity H2 (> 99.999%) or D2 (> 99.8%) to probe H- and D- ions, respectively, and examine the isotope effect within a wide range of gas pressure. These ions are predominantly formed in the bulk plasma by dissociative attachment (DA) of low-energy (cold) electrons to highly ro-vibrationally excited molecules. The latter result mainly from the radiative decay and excitation (EV) process sustained by high-energy (hot) electrons heated in the ECR zones. Langmuir probe and laser photo-detachment measurements are realized within the pressure range 0.27 to 2.67 Pa under constant microwave power (0.9 kW). It is revealed that: (i) the plasma potential, cold electron temperature, and cold electron density tend to be higher in deuterium; (ii) no pronounced difference in the hot electron density and temperature is found between the two plasmas; and (iii) overall a similar H- and D- negative ion yield (up to 6×109 cm-3; under the present conditions) is achieved. However, for equal plasma densities an isotope effect is exhibited showing higher H- density over the entire pressure range. Finally, the nH- / n ratio is constantly higher than the nD- / ne one and they both peak around 1.33 Pa.

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