Abstract
This paper reports the growth and spectral properties of Cr3+:Na2Mg5(MoO4)6 crystals. The Na2Mg5(MoO4)6 crystal was grown from a flux of Na2Mo2O7 by the top seeded solution growth method. The absorption cross-sections are 0.692×10−19cm2 at 507nm and 1.151×10−19cm2 at 736nm, respectively. The emission cross-section is 1.62×10−19cm2 at 914nm with FWHM of 192nm. Based on the absorption and emission spectra, the crystal field strength Dq, the Racah parameters B and C, effective phonon energy ℏω and the Huang–Rhys factor S were calculated. The spectral properties of Cr3+:Na2Mg5(MoO4)6 crystal demonstrate a good potential for tunable laser material.
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