Growth and structure of nematic spherulites under shallow thermal quenches

Abstract

The growth kinetics, shape, interfacial and internal orientation texture of a submicron nematic spherulite arising during the isotropic-to-nematic liquid crystal phase transformation under shallow thermal quenches is analyzed using theory, scaling, and numerical simulations based on the Landau – de Gennes model (The Physics of Liquid Crystals, 2nd edn. Clarendon, Oxford). The numerical computations from this model yield interfacial cusp formation that relaxes through the nucleation of two disclination lines of topological charge +1/2 and subsequently leads to intra-droplet texturing and a net topological charge within the spherulite of +1. The timing of these events suggests that cusp formation at the interface is intimately associated with the interfacial defect shedding mechanism (J. Chem. Phys. 124:244902, 2006) for shallow quenches. These results are different than predictions for deep quenches (J. Chem. Phys. 124:244902, 2006) where interfacial defect shedding leads to four defects and a net topological charge of +2. A liquid crystal dynamic shape equation is derived from the Landau – de Gennes model to account for the interface shape changes in terms of surface viscosity, the driving forces due to the uniaxial nematic-isotropic free energy difference, capillary forces, and friction forces, and used to semi-quantitatively show that during cusp formation and defect shedding, gradient elasticity, capillary forces and friction play significant roles in decelerating and accelerating the surface. An interfacial eigenvalue analysis shows that during the shallow quench, disclination lines nucleate within the interface itself and then texturize the nematic droplet as they migrate from within the interface to the bulk of the growing nematic droplet. After defect shedding, the spherulite is nearly circular and grows with constant velocity, in agreement with experiments. The results shed new light on intra-spherulite texturing mechanisms in phase ordering under weak driving forces.