Abstract
Piezoelectric single crystals of Pb(Mg 1/3Nb 2/3)O 3–PbTiO 3 (PMN–PT) show superior properties to piezoelectric ceramics and piezoelectric films in device applications. However, the applications of PMN–PT single crystals are limited by the lack of a simple and reproducible fabrication technique. By studying the effect of fabrication condition on the growth of PMN–PT single crystals in the flux method, we successfully obtained PMN-PT single crystals. The size of the obtained crystals varied from 1 to 4 mm, mostly showing regular cubic shape. X-ray diffraction technique identified the crystal phase was PMN–PT. Electron diffraction spectroscope analysis indicated that the composition of the single crystals was closed to the designed solid solution. The (0 0 1) single crystals showed a dielectric constant peak of 15,200 at 42°C. The crystals had a remnant polarization 16 μc/cm 2, a spontaneous polarization 22.1 μc/cm 2, and a coercive field 2.55 kV/cm. Our measurement indicated the temperature dependence and frequency dependence of the dielectric constant and dielectric loss of PMN–PT single crystals. The results will be a great help for the applications of PMN–PT single crystals.
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