Abstract
Either one or both (except when M′ = Cu) of the M(PPh 3) (M = Cu, Ag or Au) moieties in the heteronuclear metal cluster compounds [M 2Ru 4(μ 3-H) 2(CO) 12(PPh 3) 2] can be replaced by similar units, containing a different Group Ib metal M′, by treating dichloromethane solutions of the clusters with the appropriate amounts of the complexes [M′X(PPh 3)] (M′ = Cu or Au, X = Cl; M′ = Ag, X = I), in the presence of TIPF 6; the new clusters are obtained in ca. 70–80% yield.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
