Abstract

The heteronuclear cluster chemistry of the Group IB metals. Part 16. Metal exchange reactions in Group IB metal heteronuclear cluster compounds. Synthesis and structural characterization of the trimetallic hexanuclear cluster compounds [MM′Ru<sub>4</sub>(µ<sub>3</sub>-H)<sub>2</sub>{µ-Ph<sub>2</sub>P(CH<sub>2</sub>)<sub>n</sub>PPh<sub>2</sub>}(CO)<sub>12</sub>](M = Cu, M′= Ag or Au; M = Ag, M′= Au; n= 1 or 2) and X-ray crystal structure of [AuCuRu<sub>4</sub>(µ<sub>3</sub>-H)<sub>2</sub>{µ-Ph<sub>2</sub>P(CH<sub>2</sub>)<sub>2</sub>PPh<sub>2</sub>}(CO)<sub>12</sub>

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