Groundwater vulnerability assessment of elevated heavy metal contamination related health hazard in coastal multi-aquifers of Sundarban Biosphere Reserve, India

Abstract

The concept of groundwater (GW) vulnerability emerged as a response to the escalating contamination of GW globally. Over recent decades, both scholars and policymakers have extensively utilized GW vulnerability assessments to safeguard groundwater from pollution. Within the Sundarban Biosphere Reserve (SBR), inhabitants residing near coastal aquifers face significant challenges, notably the scarcity of fresh water during the hot and dry season. Furthermore, there is a concern regarding the presence of heavy metals (HMs) in this region, adversely impacting GW quality. In both Indian and global contexts, HM contamination, including arsenic (As), fluoride (F‾), and nitrate (NO3–), and its repercussions on human health (HH) in coastal districts, represent critical issues. In light of these challenges, this study aims to assess GW vulnerability and its implications for HH in SBR utilizing the Hazard Quotient (HQ) approach. Fifteen hydro-geochemical parameters have been selected for this research endeavor. Various statistical indices, such as “groundwater quality index (GWQI)”, “degree of contamination (CD)”, “index of ecological risk (ERI)”, and “human health hazard index (HHHI)”, have been employed to accomplish the study objectives. Piper's and Box plot diagrams were utilized to assess hydrogeochemical properties and GW quality. The findings reveal average concentrations of HMs, such as As, NO3–, and F‾ in the study area, to be 0.204 mg/l, 6.28 mg/l, and 0.79 mg/l, respectively. Among all variables, a positive correlation of 0.876 is observed between electrical conductivity (EC) and sodium ions (Na+). Eventually, the outcomes of this study can provide valuable insights for planners and policymakers to make informed decisions regarding the sustainable management of water resources.