Groundwater conceptual pollution model and related human health hazards, the main dilemma of a desert aquifer near ophiolite complex.

Abstract

Groundwater is a finite resource in Davarzan region which is located between the ophiolite complex mountain in the north and salty playa at the south. The water samples were analyzed to assess the origin of groundwater pollution and explain links between the disturbed heavy metals composition of the earth's surface and the human health risks. The main heavy metal pollutants in the groundwater are Cr, Fe, As and Pb ions. In general, the groundwater salinity and some elements such as Cr and As are increased along with surface topography and groundwater flow directions from the northern ophiolite highlands recharge area to the adjacent desert discharging zone in the south. Despite the ophiolite complexes being the most enriched in Cr element, the lowest Cr concentration in the groundwater was measured near the ophiolite area, which is in the range of its discharged springs. Based on the groundwater conceptual pollution model, bedrock geochemistry controls the composition of soil and hence that of groundwater. The Cr samples show a direct relation with the EC value indicating that intrusion of salinity from the salt pan is probably another reason for the increased Cr concentration. The results of health risk assessment indicated that the groundwater suffered from significant contamination and if used for long-term without pre-treatment may pose serious health risks to human population via drinking water and irrigation of agricultural fields. This is the first attempt to apply hydrogeological setting along with the source of pollution and its health risk in a desert-ophiolitic area.