Green Synthesis of a Novel Cationic Surfactant Based on an Azo Schiff Compound for Use as a Carbon Steel Anticorrosion Agent.

Abstract

The new cationic surfactant-based azo Schiff compound (azoS8) was prepared, characterized, and investigated as a corrosion inhibitor for carbon steel in 1 M HCl by means of electrochemical approaches in this study. The chemical structure of azoS8 has been verified by the FTIR and 1H NMR spectra. According to the electrochemical system, the examined surfactant is a mixed-type inhibitor. The surfactant azoS8 was an adequate corrosion inhibitor, as evidenced by the reduction in corrosion current densities and the rise in coverage of the surface identified with an evolving inhibitor amount. When the surfactant azoS8 had been added, the capacitive cycle loops on the Nyquist plots were broader, and the dimension of these loops expanded with surfactant azoS8 concentration. This implies that the amount of surfactant azoS8 led to an improvement in the impedance of the steel electrode. The surfactant azoS8 adsorption system is well suited to the Langmuir adsorption isotherm. It was discovered that azoS8 had a Gibbs free energy change value of -27.72 kJ mol-1, which is a mixed adsorption mechanism containing both physisorption and chemisorption.