Abstract
A quantitative comparison was achieved between space charge theory and segregation at grain boundaries in the model system TiO[sub 2]. The ionic space charge can be titrated from negative to positive potential. A space charge model was developed that includes the lattice defect chemistry. Defect formation energies in the Frenkel pair for TiO[sub 2] were studied. Grain boundary enthalpy was measured during coarsening. It was shown that it is the barium vacancy that forms near surfaces in donor-doped BaTiO[sub 3] electroceramics during oxidative-cooling.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
