Gold diffusion into and out of quartz-hosted fluid inclusions during re-equilibration experiments at 600–800 °C and 2 kbar

Abstract

Listen

Translate article

Fluid inclusions were synthesized in quartz and subsequently re-equilibrated in fluids of different compositions to investigate whether the Au content of fluid inclusions can be modified via Au diffusion through the host quartz. In one experiment fluid inclusions containing 5wt% KCl were synthesized in platinum capsules at 2kbar, 800°C and then re-equilibrated at the same conditions for 4days in a fluid containing 20.1wt% NaCl, 3.5wt% HCl and ~100ppm Cs enclosed in a gold capsule. LA-ICP-MS analyses of 5–10 fluid inclusions before and after the re-equilibration experiment demonstrate that the inclusions gained up to 570ppm Au and up to 0.23wt% Na during the re-equilibration process. Their unchanged high K-content and the absence of Cs within the inclusions proves that they remained physically closed during the re-equilibration, and thus that Na and Au were gained by diffusion through the quartz lattice. In a similar experiment conducted at 600°C the fluid inclusions gained up to 140ppm Au within 14days. Reverse experiments were conducted by synthesizing Au-bearing fluid inclusions in gold capsules and then re-equilibrating them in platinum capsules, which caused the inclusions to lose up to several hundred ppm Au. In both type of experiments Au diffusion appears to have been driven by chemical potential gradients of Au between the fluid inclusions and the external fluid. Additional experiments were performed to test whether Au is able to diffuse into fluid inclusions in response to loss of H+, or indirectly as a consequence of diffusional Cu-gain and corresponding formation of Cu-rich sulfide daughter crystals. However no evidence for Au uptake via such mechanisms was found.If Au concentrations in natural, quartz-hosted fluid inclusions from magmatic-hydrothermal ore deposits are affected, then they likely lost Au rather than gained it. At temperatures below 400°C diffusional loss or gain of Au is considered unlikely in magmatic-hydrothermal systems, but potentially was significant in samples from orogenic Au gold deposits.