Abstract
Vapour pressures of (1,2-dichloroethane + n-hexane or cyclohexane or n-hexadecane or tetrachloromethane or benzene) were measured at 298.15 K. Barker's method was used for calculating activity coefficients and excess molar Gibbs free energies. A maximum-boiling azeotropic mixture is produced with n-hexane, cyclohexane, or tetrachloromethane. (1,2-Dichloroethane + benzene) behaves nearly ideally and (1,2-dichloroethane + n-hexadecane) shows a high value of TS m E.
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