Giving a New Status to a Dyes Collection: A Contribution to the Chromotope Project

Abstract

Chromotope, the 19th Century Chromatic Turn, is a multidisciplinary ERC research programme that focuses on the “chromatic turn” of the 1860s in France and England, following the invention of the first synthetic dyes. This project, based on a partnership between Sorbonne University (PI: Charlotte Ribeyrol), Oxford University, and the Conservatoire national des arts et métiers (Cnam), investigates how this turn led to new ways of thinking about colour in art, literature, history, and science throughout the second half of the 19th century. One of the key aims of this research is to reappraise the role played by the Cnam in the dissemination of knowledge about synthetic dyes, from the creation in 1852 of the first chair in dyeing and printing until the Interwar period, when a collection of dyes including more than 2500 references, obtained from major European firms, was formed. A full inventory based on the description of each container has just been made together with a bibliographical research. Nevertheless, 2% of the containers are unlabeled and the reattribution of their composition is the main goal of our study. In order to set an appropriate analysis protocol to identify these orphan containers, a preliminary work was conducted on a random selection of identified dyes. For this purpose, electrospray ionization mass spectrometry and Fourier-transform infrared spectroscopy were used on 13 samples from different dye classes. The relevance of this protocol will be discussed for the identification of unknown compounds.