Abstract
• Deviation from equilibrium is recognized as a manifestation of rapid depressurization events including Rapid Phase Transitions, Boiling Liquid Expanding Vapor Explosions, and flow of saturated and slightly subcooled liquids through converging nozzles and sudden contractions. • Non-equilibrium effects are attributed to nozzle geometry and the pressure driving force for saturated and slightly subcooled liquid flow through nozzles and sudden contractions. • Bubble nucleation theory is used to estimate the deviation from equilibrium and single-phase flow methods are used to estimate the critical mass flux when rapid vaporization occurs at the nozzle throat. It is well known that homogeneous equilibrium methods for calculating the mass flux of initially subcooled or saturated liquids in short nozzles under-predict the measured values and various methods for estimating non-equilibrium effects have been presented in the past. It is shown in this paper that acceleration effects at the entrance of converging nozzles due to changing cross-sectional area and approach to thermodynamic saturation pressure at the point of maximum fluid acceleration can be the most significant causes of non-equilibrium. By properly accounting for non-equilibrium due to the fluid acceleration, single-phase flow methods can be used to estimate the pressure loss and mass flux in nozzles when rapid vaporization occurs at the nozzle throat. For these cases, choking occurs due to the rapid vaporization while the difference between the inlet pressure and choking pressure determines the nozzle mass flux.
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