Geochronology of reworked ash and its implications for accommodation space variations in distal foreland basins, McMurray Formation, Alberta, Canada

Abstract

A bentonite bed consisting of reworked volcanic ash from the Barremian to Aptian lower McMurray Formation is dated using chemical abrasion thermal ionization mass spectrometry (CA-TIMS) on zircon. The bentonite bed is from a cored interval in the McKay Paleovalley in the northern Athabasca Oil Sands Region of Alberta, Canada. Deposition of the lower McMurray Formation took place in the distal portion of the Western Canada Sedimentary Basin early in the Cretaceous-to-Paleocene phase of widespread contractional deformation in the Canadian Cordillera. A 30 g sample of volcanic ash yielded >10,000 very small (<50 µm) zircon grains with the vast majority (~99.7%) being highly abraded and clearly detrital. Twenty-six sharply faceted grains were sufficiently large to be mounted for laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) analysis, which yielded seven Lower Cretaceous dates. These Lower Cretaceous grains were further analyzed using CA-TIMS. The five youngest CA-TIMS dates agree with a weighted mean of 121.51 ± 0.11 Ma which is conservatively interpreted as a maximum depositional age (MDA). The good agreement between the five zircon dates indicates the MDA is probably the depositional age. This study demonstrates that with careful analysis of zircon populations, high-confidence MDAs can be derived even from reworked ash beds that are dominated overwhelmingly by detrital zircon. The date from this study overlaps a previously published MDA of 121.39 ± 0.27 Ma for the top of the lower McMurray Formation in Firebag Tributary in the northeastern Athabasca Oil Sands Area. The overlapping dates establish a widespread chronostratigraphic surface within the northern Athabasca Oil Sands Area. Both ages are from ash beds preserved in coal seams, suggesting that the coal-bearing interval is a regional marker bed and that the ash beds may form an intraformational datum. Further, the occurrence of the ash beds in the McMurray Formation in close proximity to regional flooding surfaces suggests that tectonic activity in the emerging Canadian Cordillera influenced accommodation space variations in the distal portions of the adjacent foreland basin.