Geochemical response of produced water in the CBM well group with multiple coal seams and its geological significance-A case study of the Songhe well group in Western Guizhou

Abstract

The geochemical response of produced water from coalbed methane (CBM) well group with multiple coal seams has rich geological significance. Taking 8 CBM wells of Songhe well group in western Guizhou as an example, the geochemical response characteristics and productivity significance of the CBM well group with multiple coal seams when inter-well interference or inter-layer interference appears have been examined mainly based on analyzing conventional ions, hydrogen and oxygen isotopes (δD and δ18O) of 7 batches of produced water samples in the stable production period of 1 year and 4 months, and dissolved inorganic carbon (DIC) stable isotopes (δ13CDIC) of 5 batches of produced water samples by cluster analysis and geological analysis methods. The study found that the change in dynamic fluid level has a good correlation with the Q-type clustering of δD-δ18O of produced water in the process of forming inter-well interference. With the formation of inter-well interference, the δD and δ18O clustering coefficient gradually decreases, and the fluids produced from the wells become more and more similar in property. In addition to the influence of drainage time, another main geological factor affecting inter-well interference is the buried depth of the coal seam. The larger the buried depth is, the larger the cumulative production of water, the faster the water circulation, the larger the Cl− concentration in produced water, the smaller the d-excess value (δD surplus index), and the smaller the cumulative production of CBM will be. In commingled CBM production of multiple coal seams, with larger span and multiple layers, inter-layer interference is likely to occur, resulting in unbalanced productivity contribution of the layers hard to tell. Because the δ13CDIC value in produced water from a well has a positive anomaly, the producing coal seams in the well are in the middle-upper layer of coal bearing strata; these coal seams have better permeability and higher water content, higher CO2 concentration and lower heavy hydrocarbon gas concentration offsetting each other, together with other geological conditions, it is concluded that the relatively large amount of CO2 formed by microbial reduction is the main cause of the positive δ13CDIC abnormality. Taking this well as the calibration well, combined with the Q-type clustering result of the δ13CDIC in produced water from the well group, considering the distribution of the developed coal seams and the change of the dynamical liquid level during the stable production period of the well group, the contribution of multi-coal layers in each well were estimated. If the cluster distance between the calibration well and another well is farther, the lower layer makes a larger contribution to the CBM productivity. If the cluster distance between the calibration well and another well is closer, the middle and upper layer contribute more to the CBM productivity, and it is mainly the production layers under the liquid level that produce CBM. This provides a unique hydrogeochemical analysis method for analyzing and identifying the contribution of production layers.