Geochemical Evaluation of the Lower Senonian Ogugu Shale, Southern Benue Trough, Nigeria: Implication for Source Richness, Quality and Petroleum Potential

Abstract

The Lower Senonian Ogugu Shale is the topmost layer of the Coniancian-Santonian depositional unit in the Southern Benue Trough. Sediments of this unit have been suggested to have huge potential for hydrocarbon generation. However, detailed geochemical studies on the organic matter source, thermal maturity and the hydrocarbon potential Ogugu Shale are still missing. For the present study, a total of 16 cuttings and 3 core samples of the Ogugu Shale from Amasiodo-1 well were subjected to total organic carbon (TOC), Rock-Eval pyrolysis and gas chromatography mass spectrometry (GC-MS) analyses in order to characterize the organic matter richness, kerogen type and liquid hydrocarbon-generative potential in the samples. The TOC values (0.70 to 1.20 wt. %) and Rock-Eval pyrolysis data S2 (0.26-0.73 mg HC/g rock) as well as its calculated parameters Hydrogen Index (HI; 23-72 mg HC/g rock) and Generative Potential (GP; 0.33-0.84 mg HC/g rock) suggest poor to fair organic rich rock containing dominantly terrestrially derived Type III kerogen. The biomarkers as well as the source-indicating aromatic hydrocarbons in the samples suggest contributions from mixed aquatic and vascular organic matter deposited under oxic-dyoxic conditions of deltaic paleoenvironment. The Rock-Eval pyrolysis Tmax (434-4560 C) including the derived vitrinite reflectance (Rc; 0.65-1.05%) indicate thermally matured source rocks. The thermal maturity status of Ogugu Shale is further supported by molecular thermal parameters from the saturate and aromatic compounds. This study therefore conclude that that the Senonian Ogugu Shale of the Southern Benue Trough contain thermally matured fair quantity of organic matter with poor hydrocarbon potential.