Abstract

In order to have a better understanding of the geochemical characteristics of gases from deep depths, gases from the clastic sandstone reservoirs in the Dabei and Keshen gas fields in the Kuqa depression, Tarim Basin, and gases from the marine carbonate reservoirs (Ordovician and Cambrian) in the craton area of Tarim Basin and Sichuan Basin (Yuanba, Longgang, Puguang gas fields) are investigated based on the molecular composition, stable carbon and hydrogen isotopes. Deep gas, either from the clastic sandstone reservoirs or from the marine carbonate reservoirs, is dominated by alkane gas. Gases from Kuqa depression and Sichuan Basin are dry gas, with high gas dryness coefficient, 0.976 and 0.999, respectively. Deep gas from the craton area in Tarim Basin includes both dry and wet gases. N2 and CO2 are the common non-hydrocarbon components in the deep gas. Gases from the continental sandstone reservoirs have no H2S, while gases from the marine carbonate reservoirs often have H2S. The relatively high δ13C2 value in the Kuqa depression indicates the gas was generated from humic type III kerogen, while the relatively low δ13C2 value in the craton area of Tarim Basin indicates most of the gas was generated from the marine sapropelic organic matter. Deep gas in Sichuan Basin, which has medium δ13C2 value, was generated from both humic type III and sapropelic type II organic matter. Carbon isotopic anomaly such as partial carbon isotopic reversal or relatively heavy carbon isotope is common in the deep gas, which is caused by secondary alteration. Gases from the Dabei gas field have a mean δ2H1 value of –156‰, while gases from the craton area of Tarim Basin, and Yuanba and Puguang gas fields in Sichuan Basin have relatively heavier δ2H1 value, i.e., average at −130 and −122‰, respectively. The abnormally heavier δ2H1 value in Dabei gas field is due to the high thermal maturity and possible saline depositional environment of the source rocks. This study performed a comprehensive comparison of the geochemical characteristics of the deep gases with different origins, which may provide a hint for future exploration of deep gas in the world.

Highlights

  • After massive exploitation of conventional oil and gas, exploration has been increasingly difficult and more attention has been paid to the deep and ultra-deep resources, especially in the mature exploration area, deep and ultra-deep area has been a significant target

  • The geothermal gradient is 2.26◦C/100 m (Feng et al, 2009) and 2.28◦C/100 m (Xu et al, 2011) in the Tarim and Sichuan basins, respectively, so in these two basins, deep gas is referred to the gas with reservoir depth greater than 4,500 m and ultra-deep gas is referred to the gas with reservoir depth greater than 6,000 m (Dai et al, 2018)

  • Taking −28 of δ13C2 as a cut-off value, combined with the δ13C1 vs. δ13C2 diagram (Figure 6), gas from the continental sandstone reservoirs in the Dabei and Keshen gas fields in the Kelasu thrust belt in the Kuqa depression were generated from the type III kerogen and belong to coal-derived gas (Zhang et al, 2011; Dai et al, 2014; Wang, 2014; Wei et al, 2019), gases from the marine carbonate reservoirs (Ordovician and Cambrian) in the craton area in the Tarim Basin are mostly sourced from the sapropelic organic matter and belong to oil-related gas (Wang et al, 2014; Zhu et al, 2014; Chen F. et al, 2018)

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Summary

Introduction

After massive exploitation of conventional oil and gas, exploration has been increasingly difficult and more attention has been paid to the deep and ultra-deep resources, especially in the mature exploration area, deep and ultra-deep area has been a significant target. Gases from Kela2 gas field have the heaviest carbon isotope of methane

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