Geochemical characteristics of saline soils formed during the recent retreat of the Caspian Sea

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The objectives of this study are: 1- Determining geochemical characteristics and soil formation processes that lead to soil salinity. 2- To investigate the variability of soil properties across different geomorphic units. The coastal landforms of the Caspian Sea have experienced several seawater retreat and progress in recent decades, which has caused changes in terms of pedology and geomorphology. Routine soil properties, including soil cations and anions (Ca2+, Mg2+, Na+, K+, Cl-, SO42-, CO32–, and HCO3–), and total and available forms of some micro-elements (Fe, Mn, Zn, and Cu) of 136 samples collected from 0-20 cm of soils were analyzed according to standard methods. Mapping of the obtained results was done using inverse distance weighting (IDW) in ArcGIS 10.8. The results showed that although the main source of cations and anions in the soil solution is seawater, their concentration and changes in the soil solution are different depending on the processes carried out in soil. Mg2+, Na+, and Cl- were highly enriched in saturated soil extracts compared to seawater (261 %, 153 %, and 149 % respectively). While, K+ and Ca2+, increased by 81 % and 47 % accordingly, and HCO3– and SO42-, decreased by −56 % and −25 % due to precipitation of carbonate and gypsum in the soil. Total and available forms of micro-nutrients were high across the study area. The distribution pattern of the total micro-nutrients follows the type of landforms (affecting drainage condition) and their clay contents (mineralogical composition and abundance), however, the available form of micro-nutrients depends on soil moisture conditions and proximity or distance to the coastline. The results showed that the chemistry of seawater is the main factor controlling the chemical and physical properties of soils and their distribution patterns. The geochemical processes of soil formation cause special interactions between the components of soil solution, which leads to the removal of carbonate, bicarbonate, and sulfate from the soil solution and precipitation with calcium as calcium carbonate and calcium sulfate.