Abstract

The phenomenon of generating harmonic oscillations by systems formed of iron, zinc, copper, and aluminum or magnesium and a 0.5 M sulfuric acid solution under conditions of the spontaneous dissolution of metals is investigated. The corrosion–electrochemical circuit was found to generate resonance oscillations as a master oscillator. The oscillation frequency depends both on the parameters of electronic scheme and the corrosion–electrochemical properties of a system itself. The frequencies studied (f) range from 5 to 50 kHz. The parameters of resonance oscillations are determined by the corrosion–electrochemical characteristics of the electrode used. The technique developed supposedly supplements the electrochemical impedance spectroscopy and provides new prospects in developing the technique of resonance spectrometry.

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