Abstract

A rapid thermal annealing (RTA) treatment was used to improve the performance of ammonia sensors based on a MOSFET structure with a thin SnO 2 layer used as a gate. RTA processes in vacuum with duration of 15–60 s and temperatures 600–800°C were applied. After thermal treatment samples are subjected to a cycle of successive steps with different environmental conditions in order to reveal the sensitivity, selectivity and reversibility of the response. It is found that the RTA process at 800°C, with duration of 60 s, rise time of 2 s and fall time of 4 s results in enhanced sensitivity to the active agent (NH 3), reduced cross-sensitivity to water vapours (relative humidity) and improved reversibility of the device's response. This overall improvement of the performance is explained by surface changes of the SnO 2 layer, provoked by the RTA process. Such changes are revealed by reflection high-energy electron diffraction (RHEED) and scanning electron microscopy (SEM).

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