Functionalized SiC nanocrystals for tuning of optical, thermal, mechanical and electrical properties of polyvinyl alcohol

Abstract

Polyvinyl alcohol (PVA)-SiC nanocomposite films were prepared by incorporating functionalized Silicon Carbide (f-SiC) nanocrystals in PVA matrix. Structural characterization of SiC nanocrystals before and after the functionalization was carried out using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and Thermogravimetric analysis (TGA). Transmission electron microscopy (TEM) and Scanning Electron Microscopy (SEM) were used to study the morphology and size distribution of f-SiC nanocrystals in PVA-SiC nanocomposite films. TEM and SEM images depict an improved dispersion of f-SiC nanocrystals in PVA matrix. UV–Visible absorption spectroscopy was employed to study the optical properties such as absorption coefficient (α), optical energy gap (Eg), Urbach's energy (Eu), refractive index (n) and dielectric constant of PVA and PVA-SiC nanocomposite films. Refractive index of PVA, at 550nm wavelength, increased from 1.7 to 2.2 for PVA-SiC nanocomposite film containing 0.023wt% f-SiC nanocrystals. TGA shows that the onset of thermal decomposition of PVA is only slightly affected by the addition of f-SiC nanocrystals. Knoop microhardness number has increased from 23MPa for PVA to 45MPa for PVA-SiC nanocomposite film containing 0.023wt% f-SiC nanocrystals at an applied load of 9.8mN indicating improved interfacial interaction. Current-voltage analysis indicated an increase in conductivity of PVA with the introduction of f-SiC nanocrystals. The conduction mechanism responsible for charge transport in PVA-SiC nanocomposite films was found to be voltage dependent. Schottky mechanism is the dominant conduction mechanism at high voltages whereas Poole Frenkel mechanism dominates at low voltages.