Abstract
Kapok fibre has the advantage of low density, low porosity and low thermal conductivity, which make it an excellent substitute for fumed silica and environmentally-unfriendly synthetic polymers as core material of vacuum insulation panels (VIP). However, kapok fibre is hydrophobic, consequently, kapok fibre core materials made by conventional wet forming with weakly-bound fibres and large voids that shorten their service life. Lignin is a natural and sustainable material that has good hydrophilicity and small particle size to form nano-porous networks. Therefore, we herein present the incorporation of lignin in kapok fibre to generate a composite core material with hierarchical porous structure. Lignin functionalises the kapok fibre surface to make it hydrophilic and dispersible in water. Simultaneously, lignin enhances the mechanical properties and service life of core material by transforming its internal microstructure. The effective thermal conductivity of prepared VIP is below 6.00 mW/(m∙K), and after 28 days of accelerated ageing test without desiccant or getter, the effective thermal conductivity increases less than 5.00 mW/(m∙K). Interestingly, the addition of lignin also reduces radiative heat transfer in the VIP. So, lignin addition enables high-performance VIP to be produced. Moreover, as a natural material, kapok fibre is low-cost, environmentally-friendly, sustainable, and energy-efficient.
Published Version
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